CRYSTAL CHEMISTRY AND POLYTYPISM OF TYROLITE
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dc.contributor.author | Krivovichev S.V. | |
dc.contributor.author | Chernyshov D.Yu. | |
dc.contributor.author | Dobelin N. | |
dc.contributor.author | Armbruster T. | |
dc.contributor.author | Kahlenberg V. | |
dc.contributor.author | Kaindl R. | |
dc.contributor.author | Ferraris G. | |
dc.contributor.author | Tessardi R. | |
dc.contributor.author | Kaltenhauser G. | |
dc.date.accessioned | 2024-07-14T10:19:04Z | |
dc.date.available | 2024-07-14T10:19:04Z | |
dc.date.issued | 2006 | |
dc.identifier | https://elibrary.ru/item.asp?id=13504869 | |
dc.identifier.citation | American Mineralogist, 2006, 91, p. 1378–1384 | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/44414 | |
dc.description.abstract | The crystal structures of the 1M and 2M polytypes of tyrolite have been solved from single-crystal X-ray diffraction data. The structure of tyrolite-1M [monoclinic, P2/c, a = 27.562(3), b = 5.5682(7), c = 10.4662(15) Å, β = 98.074(11)°, V = 1590.3(3) Å 3 ] has been refined to R1 = 0.086 on the basis of 2522 unique observed reflections collected using synchrotron radiation at the Swiss-Norwegian beamline BM01 of the European Synchrotron Research Facility (SNBL at the ESRF). The structure of tyrolite-2M [monoclinic, C2/c, a = 54.520(6), b = 5.5638(6), c = 10.4647(10) Å, β = 96.432(9)°, V = 3154.4(6) Å 3 ] has been refined to R1 = 0.144 on the basis of 2666 unique observed reflections obtained from a non-merohedrally twinned crystal using in-house X-ray radiation and a STOE IPDS II image-plate diffractometer. The structures are based upon complex nanolayers consisting of Cu, As, and Ca coordination polyhedra. The core of the nanolayer is a copper arsenate substructure consisting of A and B sublayers. The B sublayer consists of chains of edge-sharing Cu octahedra running along the b axis. The A sublayer contains trimeric units of Cu octahedra sharing corners with AsO 4 tetrahedra. Two adjacent A sublayers are linked by the octahedral chains of the B sublayer resulting in formation of the 18 Å thick ABA slab. The ABA slab is sandwiched between sublayers of Ca2+ cations and H2O molecules. Adjacent nanolayers are connected by hydrogen bonds to the interlayer species (carbonate anions and H2O molecules). The structures of tyrolite-1M and tyrolite-2M differ by the stacking sequence of the nanolayers only. The adjacent nanolayers in tyrolite-2M are shifted by b/2 = 2.8 Å in comparison to the relative position of the nanolayers in tyrolite-1M. The structural formula of tyrolite can be written as [Ca2 Cu9(AsO 4)4 (OH) 8(CO 3)(H 2 O) 11 ](H 2O)x where x = 0–1. | |
dc.title | CRYSTAL CHEMISTRY AND POLYTYPISM OF TYROLITE | |
dc.type | Статья | |
dc.identifier.doi | 10.2138/am.2006.2040 |
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