TRANSMISSION ELECTRON MICROSCOPE OBSERVATIONS OF ILLITE POLYTYPISM
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dc.contributor.author | Grubb S.M.B. | |
dc.contributor.author | Peacor D.R. | |
dc.contributor.author | Jiang W.T. | |
dc.date.accessioned | 2020-11-06T09:14:07Z | |
dc.date.available | 2020-11-06T09:14:07Z | |
dc.date.issued | 1991 | |
dc.identifier | https://elibrary.ru/item.asp?id=31604772 | |
dc.identifier.citation | Clays and Clay Minerals, 1991, , 5, 540-550 | |
dc.identifier.issn | 0009-8604 | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/18565 | |
dc.description.abstract | Transmission electron microscopy (TEM), including selected area electron diffraction (SAED), has been used to identify polytypes in iUite, phengite and muscovite from samples representing a wide range of diagenesis and low-temperature metamorphism. Samples include Gulf Coast sediments, sedi- ments from the Salton Sea region, California, the Martinsburg Formation at Lehigh Gap, Pennsylvania, the Kalkberg Formation at Catskill, New York, Otago Schists from southern New Zealand, pelites from the Gasp6 Peninsula in Quebec, Canada, shales and slates from Wales, sediments from the Barbados accretionary complex, and synthetic hydrothermal illite. Samples from rocks of lowest grades, including those representing a range of sedimentary diagenesis, invariably give SAED patterns with few, complex non-001 reflections which are diffuse and ill-defined and that represent largely disordered stacking sequences. Corresponding XRD patterns are consistent with 1M~ polytypism. The term 1Md is therefore retained for this material. Higher grade samples, including those in which slaty cleavage is developed, and detrital grains in low-grade sediments invariably give diffraction patterns of well-ordered 2- or 3-layer polytypes. Of all samples and localities studied, only one diffraction pattern, from a sample in the Gasp6 sequence, was found to be predominantly 1M. In none of the other sequences included in this study were any 1M or predominantly 1M electron diffraction patterns obtained for illite grains. Where illite is in its original state of formation, it is consistently IMd, whether it originates as a result of direct crystallization from solution or as a replacement of smectite. Where illite has apparently un- dergone subsequent change, presumably through dissolution and crystallization representing an Ostwald- step-rule-like change, it occurs as a well-ordered 2-layer (inferred to be 2M,) or, less commonly, a 3T polytype. On the basis of this limited survey, the state of polytypism appears to directly identify iUite as either being in, or changed from, its initial state of formation. | |
dc.title | TRANSMISSION ELECTRON MICROSCOPE OBSERVATIONS OF ILLITE POLYTYPISM | |
dc.type | Статья |
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