TRATTNERITE, (FE,MG)2(MG,FE 3[SI12O30], A NEW MINERAL OF THE MILARITE GROUP: MINERAL DATA AND CRYSTAL STRUCTURE
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dc.contributor.author | Postl W. | |
dc.contributor.author | Bojar H.-P. | |
dc.contributor.author | Walter F. | |
dc.contributor.author | Ettinger K. | |
dc.contributor.author | Hauzenberger C. | |
dc.date.accessioned | 2022-04-10T07:49:16Z | |
dc.date.available | 2022-04-10T07:49:16Z | |
dc.date.issued | 2004 | |
dc.identifier | https://www.elibrary.ru/item.asp?id=14142416 | |
dc.identifier.citation | European Journal of Mineralogy, 2004, 16, 2, 375-380 | |
dc.identifier.issn | 0935-1221 | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/36963 | |
dc.description.abstract | The new mineral trattnerite, (Fe,Mg)2(Mg,Fe)3[Si12O30], a member of the milarite group, occurs in small cavities of a Sirich xenolith at the haüyne-nephelinite quarry Stradner Kogel, eastern Styria, Austria. Trattnerite is hexagonal and forms hypidiomorphic, short prismatic to tabular crystals up to 1 mm. Associated minerals are sanidine, tridymite, quartz, hematite, orthoand clinopyroxene and clinoamphibole. The colour is pleocroitic deep blue (ω) to yellowish-green (ε), the streak is white and the crystals have a vitreous luster. Optically, the mineral is uniaxial (-), ω = 1.589(1), ε = 1.586(1) at 589 nm. The cleavage parallel to (001) is good, poor parallel to (100), and the tenacity is brittle. Trattnerite is hexagonal, P6/mcc, with unit cell parameters a = 10.050(1) Ã, c = 14.338(2) Ã, V = 1254.1(1) Ã3, Z = 2 and Dcalc. = 2.68 g/cm3. The strongest lines in the X-ray powder diffraction pattern (dobs in Ã, (hkl), I) are: 8.70, (100), 97; 7.17, (002), 100; 5.535, (102), 96; 5.026, (110), 61; 3.207, (211), 85. Two single-crystal structure refinements (R(F) = 0.028 and 0.025) of trattnerite yielded following site occupancies: the T1 tetrahedron of the double-ring unit is fully occupied by Si, the T2 tetrahedron and the A octahedron have a mixed (Mg,Fe) occupation with Fe predominantly in A and Mg in T2. The T2-O and A-O bond lengths indicate most of the iron to be in the trivalent state which is in accordance with the empirical formula: C(K0.07Na0.01)0.08A,T2(Mg2.46Fe3+1.99Fe2+0.30Mn0.08Zn0.05Al0.04Ti0.01)4.93T1Si12O30], obtained by a combination of electron microprobe data and LA-ICP-MS. The C-site located between consecutive double-ring units is occupied only by small amounts of K, the remaining 88-95 % being vacancies, which lead to increased C-O distances of 3.123 and 3.118 Ã. Trattnerite could be described as an end member in the series merrihueite-trattnerite with the chemical substitution Fe3+ + [] = Fe2+ + (K+Na)+. | |
dc.subject | trattnerite | |
dc.subject | new mineral | |
dc.subject | milarite group | |
dc.subject | Mg-Fe-silicate | |
dc.subject | crystal structure | |
dc.title | TRATTNERITE, (FE,MG)2(MG,FE 3[SI12O30], A NEW MINERAL OF THE MILARITE GROUP: MINERAL DATA AND CRYSTAL STRUCTURE | |
dc.type | Статья |
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