| dc.creator |
Gurzhiy, Vladislav V. |
|
| dc.creator |
Tyumentseva, Olga S. |
|
| dc.creator |
Krivovichev, Sergey V. |
|
| dc.creator |
Tananaev, Ivan G. |
|
| dc.date |
2016-05-06T12:40:31Z |
|
| dc.date |
2016-05-06T12:40:31Z |
|
| dc.date |
2015-05 |
|
| dc.date.accessioned |
2019-03-31T11:39:19Z |
|
| dc.date.available |
2019-03-31T11:39:19Z |
|
| dc.identifier |
1521-3749 |
|
| dc.identifier |
10.1002/zaac.201500208 |
|
| dc.identifier |
http://hdl.handle.net/11701/2242 |
|
| dc.identifier.uri |
https://repository.geologyscience.ru/handle/123456789/1874 |
|
| dc.description |
The hybrid organic-inorganic uranyl selenate, [K@(C10H20O5)][(UO2)(SeO4)(HSeO4)(H2O)] (I), was prepared by isothermal evaporation from aqueous solutions. The crystal structure of I [orthorhombic, Pnma, a = 15.386(3), b = 10.771(2), c = 13.239(3) Å, V = 2194.0(7) Å3, Z = 4, R1 = 0.042] is based upon complex 15-crown-5-ether-uranyl-selenate polymeric units consisting of uranyl selenate chains decorated by [K@(15-crown-5)]+ complexes via strong ionic K+–O bonds. The 1D hybrid units are packed in a parquetted-like fashion and connected to each other by hydrogen bonds and residual van der Waals interactions. |
|
| dc.description |
This work was supported by St. Petersburg State University (grant 3.38.136.2014) and President of Russian Federation grant for young scientists (no. MK-1737.2014.5 to V. V. G.). The XRD studies have been performed at the X-ray Diffraction Centre of St. Petersburg State University. |
|
| dc.language |
en |
|
| dc.publisher |
Wiley |
|
| dc.relation |
Zeitschrift für anorganische und allgemeine Chemie;V. 641. Issue 6 |
|
| dc.subject |
Uranyl selenate |
|
| dc.subject |
Crown ether |
|
| dc.subject |
Potassium |
|
| dc.subject |
Topology |
|
| dc.subject |
Crystal structure |
|
| dc.title |
Hybrid One-Dimensional 15-Crown-5-ether-uranyl-selenate Polymers in [K@(C10H20O5)][(UO2)(SeO4)(HSeO4)(H2O)]: Synthesis and Characterization |
|
| dc.type |
Article |
|