Cu3(SeO4)2(SeO3OH)2(H2O)16 – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds

dc.creator	Gurzhiy, Vladislav V.
dc.creator	Al-Shuray, Alexander A.
dc.creator	Britvin, Sergey N.
dc.creator	Krivovichev, Sergey V.
dc.date	2016-05-06T12:48:38Z
dc.date	2016-05-06T12:48:38Z
dc.date	2015-11
dc.date.accessioned	2019-03-31T11:39:20Z
dc.date.available	2019-03-31T11:39:20Z
dc.identifier	1099-0682
dc.identifier	10.1002/ejic.201500927
dc.identifier	http://hdl.handle.net/11701/2243
dc.identifier.uri	https://repository.geologyscience.ru/handle/123456789/1875
dc.description	Cu3(SeO4)2(SeO3OH)2(H2O)16 (1) is a novel copper selenate hydrate and the first inorganic compound to contain linear octahedral–tetrahedral heptamers. The heptamers are formed by successive polymerization of two SeO3OH tetrahedra, two SeO4 tetrahedra, and three Cu(H2O)4O2 octahedra. The linkages between the octahedra and tetrahedra are in the trans-configuration, which is in agreement with the Jahn–Teller distortion of the octahedral coordination geometry of Cu2+.
dc.description	This work was supported by the Russian Science Foundation (grant 14-17-00071). X-ray diffraction studies have been carried out at the XRD Centre of Saint-Petersburg State University.
dc.language	en
dc.publisher	Wiley
dc.relation	European Journal of Inorganic Chemistry;V. 2015. Issue 32
dc.subject	Copper
dc.subject	Chalcogens
dc.subject	Heptamers
dc.subject	Jahn–Teller distortion
dc.subject	Structure elucidation
dc.title	Cu3(SeO4)2(SeO3OH)2(H2O)16 – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds
dc.type	Article