The deprotonation and iron complexation of the hydroxamate siderophore, desferrioxamine B (desB), and a model hydroxamate ligand, acetohydroxamic acid (aHa), were studied using infrared, resonance Raman and UV-vis spectroscopy. ...
The magnitude of equilibrium iron isotope fractionation between Fe(H2O)63+ and Fe(H2O) 62+ is calculated using density functional theory (DFT) and compared to prior theoretical and experimental results. DFT is a quantum ...