This paper describes a preliminary study that attempts to determine the oxidation state of Fe (Fe3+/∑Fe) with the electron microprobe (EMP) by measuring the self-absorption induced shift of the FeLα peak emitted from ...
Fialin M.; Bézos A.; Humler E.; Wagner C.; Magnien V.(2004)
The presence of an unfilled 3d electron shell in the transition metals of the first series is manifested in X-ray self-absorption effects that cause distortions in the L emission spectra. In particular, one observes peak ...