Topologically and geometrically flexible structural units in seven new organically templated uranyl selenates and selenite–selenates - (:unkn) unknown (Elsevier, 2019)
Single crystals of seven novel uranyl oxysalts of selenium with protonated methylamine molecules, [C2H8N]2[(UO2)(SeO4)2(H2O)] (I), [C2H8N]2[(UO2)2(SeO4)3(H2O)] (II), [C4H15N3][H3O]0.5[(UO2)2(SeO4)2.93(SeO3)0.07(H2O)](NO3)0.5 (III), [C2H8N]3[H5O2][(UO2)2(SeO4)3(H2O)2]2(H2O)5 (IV), [C2H8N]2[H3O][(UO2)3(SeO4)4(HSeO3)(H2O)](H2SeO3)0.2 (V), [C4H12N]3[H3O][(UO2)3(SeO4)5(H2O)] (VI), and [C2H8N]3(C2H7N)[(UO2)3(SeO4)4(HSeO3)(H2O)] (VII) have been prepared by isothermal evaporation from aqueous solutions. Their crystal structures have been solved by direct methods and their uranyl selenate and selenite–selenate units investigated using black-and-white graphs from the viewpoints of topology of interpolyhedral linkages and isomeric variations. The crystal structure of IV is based upon complex layers with unique topology, which has not been observed previously in uranyl selenates. Investigations of the statistics and local distribution of the U–Obr–Se bond angles demonstrates that shorter angles associate with undulations, whereas larger angles correspond to planar areas of the uranyl selenite layers.
This work was supported by St. Petersburg State University (internal grant 3.38.136.2014), President of Russian Federation grant for young scientists (no. MK-1737.2014.5 to VVG) and Russian Foundation for Basic Research (grant 12-05-33097 to VMK). X-ray diffraction studies were carried out in the X-ray Diffraction Centre of St. Petersburg State University.
Keywords: Uranyl; Selenate; Crystal structure; Topology; Isomerism; X-ray diffraction