ACCURATE AND PRECISE DETERMINATION OF LI ISOTOPIC COMPOSITIONS BY MULTI-COLLECTOR SECTOR ICP-MS

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dc.contributor.author Tomascak P.B.
dc.contributor.author Carlson R.W.
dc.contributor.author Shirey S.B.
dc.date.accessioned 2021-01-09T02:42:59Z
dc.date.available 2021-01-09T02:42:59Z
dc.date.issued 1999
dc.identifier https://elibrary.ru/item.asp?id=127902
dc.identifier.citation Chemical Geology, 1999, , 1, 145-154
dc.identifier.issn 0009-2541
dc.identifier.uri https://repository.geologyscience.ru/handle/123456789/22398
dc.description.abstract A new method is presented for the preparation of geological materials (water and rock) and their accurate analysis, by multiple collector magnetic sector ICP-MS, for the isotopic composition of lithium. Based on multiple duplicate and replicate measurements over an 8-month period, the precision of this technique is conservatively estimated to be +/-1.1%% (2σ population), which is similar to the precision of other methods in current use. The δ7Li (7Li/6Li relative to the L-SVEC standard) determined for Pacific seawater is +31.8. The δ7Li of the basalt standards JB-2 and SRM-688 are +5.1 and +2.8, respectively. The new technique has additional advantages over other methods in small sample size (~40 ng Li), rapid analysis (~2 samples/h) and relative insensitivity to trace element contamination of analyte solutions.
dc.subject LITHIUM ISOTOPES
dc.subject MAGNETIC SECTOR
dc.subject ICP-MS
dc.subject CATION EXCHANGE
dc.subject MASS FRACTIONATION
dc.title ACCURATE AND PRECISE DETERMINATION OF LI ISOTOPIC COMPOSITIONS BY MULTI-COLLECTOR SECTOR ICP-MS
dc.type Статья


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