SOLUBILITIES OF PT AND RH IN A HAPLOBASALTIC SILICATE MELT AT 1300°C - APPLICATIONS TO THE ANALYSIS OF HOMOGENEOUS SAMPLES
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dc.contributor.author | Ertel W. | |
dc.contributor.author | O'Neill H.S.C. | |
dc.contributor.author | Sylvester P.J. | |
dc.contributor.author | Dingwell D.B. | |
dc.date.accessioned | 2021-01-17T00:09:22Z | |
dc.date.available | 2021-01-17T00:09:22Z | |
dc.date.issued | 1999 | |
dc.identifier | https://elibrary.ru/item.asp?id=171063 | |
dc.identifier.citation | Geochimica et Cosmochimica Acta, 1999, 63, 16, 2439-2449 | |
dc.identifier.issn | 0016-7037 | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/23278 | |
dc.description.abstract | The solubilities of Platinum (Pt) and Rhodium (Rh) in a haplobasaltic melt (anorthite-diopside eutectic composition) have been determined experimentally by using the mechanically assisted equilibration technique at 1300°C, as a function of oxygen fugacity (10-12 < fO2 =< 1 bar), imposed by CO-CO2, N2-H2-H2O, Ar-O2, and air gas mixtures. Samples were analyzed by sample nebulization (SN) inductively coupled plasma-mass spectrometry and, using some of these samples as standards, also by laser ablation (LA) inductively coupled plasma-mass spectrometry. The latter is a true microanalytical technique that allows small-scale sample heterogeneity to be detected. At each oxygen fugacity step, a time-series of samples was taken, to demonstrate that the solubilities converge on a constant value. In addition, solubilities were measured after both increasing and decreasing the imposed fO2.The results fall into three groups, according to oxygen fugacity. At high fO2s, (fO2 =< 10-2 bars), samples are homogenous at all sampling scales. Both Pt and Rh predominantly dissolve in the silicate melt as 2+ species, with some evidence for Pt4+ and Rh3+ at the highest fO2s studied (air and pure O2). From these data, we obtained the following expressions for the solubilities of Pt and Rh:Pt/ppb = 2100(fO2) + 10980(fO2)1/2Rh/ppb = 68630(fO2)3/4 + 31460(fO2)1/2At fO2 < 10-5 bars, the true solubilities of Pt and Rh appear to be obscured by Pt-Rh micronuggets, which remain suspended in the melt despite stirring on time scales of 103 h, resulting in samples that are heterogenous on the laser sampling scale. Samples at intermediate fO2 (10-2 to 10-5 bars) are affected by the micronugget problem on the sampling scale of the conventional SN-inductively coupled plasma mass spectrometry, but these can be filtered out by analyzing on the laser sampling scale. | |
dc.title | SOLUBILITIES OF PT AND RH IN A HAPLOBASALTIC SILICATE MELT AT 1300°C - APPLICATIONS TO THE ANALYSIS OF HOMOGENEOUS SAMPLES | |
dc.type | Статья |
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