ISOTOPICALLY EXCHANGEABLE ORGANIC HYDROGEN IN COAL RELATES TO THERMAL MATURITY AND MACERAL COMPOSITION
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dc.contributor.author | Mastalerz M. | |
dc.contributor.author | Schimmelmann A. | |
dc.date.accessioned | 2021-04-19T23:58:28Z | |
dc.date.available | 2021-04-19T23:58:28Z | |
dc.date.issued | 2002 | |
dc.identifier | https://www.elibrary.ru/item.asp?id=1104986 | |
dc.identifier.citation | Organic Geochemistry, 2002, 33, 8, 921-931 | |
dc.identifier.issn | 0146-6380 | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/28091 | |
dc.description.abstract | Hydrogen isotopic exchangeability (Hex) and δDn values of non-exchangeable organic hydrogen were investigated in coal kerogens ranging in rank from lignite to graphite. The relative abundance of Hex is highest in lignite with about 18% of total hydrogen being exchangeable, and decreases to around 2.5% in coals with Ro of 1.7 to ca. 5.7%. At still higher rank (Ro > 6%), Hex increases slightly, although the abundance of total hydrogen decreases. δDn is influenced by original biochemical D/H ratios and by thermal maturation in contact with water. Therefore, δDn does not show an overall consistent trend with maturity. | |
dc.title | ISOTOPICALLY EXCHANGEABLE ORGANIC HYDROGEN IN COAL RELATES TO THERMAL MATURITY AND MACERAL COMPOSITION | |
dc.type | Статья |
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