ISOTOPICALLY EXCHANGEABLE ORGANIC HYDROGEN IN COAL RELATES TO THERMAL MATURITY AND MACERAL COMPOSITION

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dc.contributor.author Mastalerz M.
dc.contributor.author Schimmelmann A.
dc.date.accessioned 2021-04-19T23:58:28Z
dc.date.available 2021-04-19T23:58:28Z
dc.date.issued 2002
dc.identifier https://www.elibrary.ru/item.asp?id=1104986
dc.identifier.citation Organic Geochemistry, 2002, 33, 8, 921-931
dc.identifier.issn 0146-6380
dc.identifier.uri https://repository.geologyscience.ru/handle/123456789/28091
dc.description.abstract Hydrogen isotopic exchangeability (Hex) and δDn values of non-exchangeable organic hydrogen were investigated in coal kerogens ranging in rank from lignite to graphite. The relative abundance of Hex is highest in lignite with about 18% of total hydrogen being exchangeable, and decreases to around 2.5% in coals with Ro of 1.7 to ca. 5.7%. At still higher rank (Ro > 6%), Hex increases slightly, although the abundance of total hydrogen decreases. δDn is influenced by original biochemical D/H ratios and by thermal maturation in contact with water. Therefore, δDn does not show an overall consistent trend with maturity.
dc.title ISOTOPICALLY EXCHANGEABLE ORGANIC HYDROGEN IN COAL RELATES TO THERMAL MATURITY AND MACERAL COMPOSITION
dc.type Статья


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