GOLD SOLUBILITY, SPECIATION, AND PARTITIONING AS A FUNCTION OF HCL IN THE BRINE-SILICATE MELT-METALLIC GOLD SYSTEM AT 800°C AND 100 MPA

Abstract

A vapor-undersaturated synthetic brine was equilibrated with metallic gold and a haplogranitic melt at 800°C and 100 MPa to examine the solubility, speciation and partitioning of gold in the silicate melt-brine-metallic gold system. The starting composition of the NaCl-KCl-HCl-H2O brine was 70 wt.% NaCl (equivalent) with starting KCl/NaCl ranging from 0.5 to 1. KCl/HCl was varied from 3.2 to 104 to evaluate the solubility and partitioning of gold as a function of the concentration of HCl in the brine. Inclusions of brine were trapped in a silicate glass during quench. Inclusion-poor and inclusion-rich portions of glass were analyzed for gold and chloride by using neutron activation analysis. The inclusion-poor glass yielded an estimate of the solubility of gold and chloride in the silicate melt. The solubility of gold in the melt, at gold metal saturation, was estimated as ~1 ppm. The solubility of gold in the brine was estimated by mass balance, given the concentration of gold and chloride in the inclusion-poor and inclusion-rich glasses. The solubility of gold metal at low-HCl concentrations in the brine, CHClb, (3 x 103 to 1.1 x 104 ppm) is ~40 ppm (by weight) and is independent of the HCl concentration under those conditions. For CHClb of 1.1 x 104 to 4.0 x 104 ppm, the solubility of gold increased from 40 to 840 ppm, and the solubility is given by: log CAub = [2.2 . log CHClb] - 7.2(1) These data suggest that a significant amount of gold is not chloride complexed in brines at low-HCl concentrations (< 1.1 x 104 ppm), but that gold-chloride complexes, possibly AuCl2H, are important at elevated concentrations of HCl (> 1.1 x 104 ppm). The calculated Nernst partition coefficient (DAub/m) for gold between a brine and melt varied from 40 to 830 over a range of brine HCl concentrations of 3 x 103 to 1.1 x 104 ppm. Our results indicate a significant amount of gold can be transported by a brine in the magmatic-hydrothermal environment independent of the fugacity of sulfur in the system. Thus brines provide an effective mechanism for the scavenging of gold from a crystallizing melt and transport into an associated magmatic-hydrothermal system, regardless of their sulfur contents.