CHARACTERIZATION OF SMECTITE AND ILLITE BY FTIR SPECTROSCOPY OF INTERLAYER NH+4 CATIONS
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dc.contributor.author | Pironon J. | |
dc.contributor.author | Mosser-Ruck R. | |
dc.contributor.author | Pelletier M. | |
dc.contributor.author | De Donato P. | |
dc.date.accessioned | 2021-11-27T03:01:31Z | |
dc.date.available | 2021-11-27T03:01:31Z | |
dc.date.issued | 2003 | |
dc.identifier | https://www.elibrary.ru/item.asp?id=13973882 | |
dc.identifier.citation | Clay Minerals, 2003, 38, 2, 201-211 | |
dc.identifier.issn | 0009-8558 | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/32494 | |
dc.description.abstract | FTIR spectroscopy has been applied to NH⁺4-exchanged dioctahedral clay minerals to determine the molecular environment of NH⁺4 and to quantify N concentration. FTIR under vapour-pressure control, coupled with heating and freezing treatments has shown that NH⁺4 ion symmetry varies with the nature of clay minerals. NH⁺4 has a perfect tetrahedral symmetry in hydrated or dehydrated smectites and belongs to the T d symmetry group.The NH⁺4-bending vibration is centred at 1450 and 1425 cm⁻¹. The Si⁴⁺-Al³⁺ substitution in dioctahedral clay minerals induces the loss of symmetry elements of the NH⁺4 tetrahedron which acquires a C 2v symmetry. As a consequence, the T d-C 2v transition can be used to characterize the smectite-illite transition. Quantification of NH⁺4 content per half unit cell is provided by n NH4 = k[NH4]/[OH] where [NH4]/[OH] is the band area ratio of the NH⁺4-bending vibration to the OH-stretching vibration. k = 1.1 for hydrated smectite, 0.9 for dehydrated smectite and 0.8 for illite or tobelite. The bending vibration of NH⁺4 is chosen for the calculation because it is not affected by superimposed contributions. | |
dc.subject | ammonium | |
dc.subject | smectite | |
dc.subject | illite | |
dc.subject | tobelite | |
dc.subject | IR spectroscopy | |
dc.subject | hydration | |
dc.title | CHARACTERIZATION OF SMECTITE AND ILLITE BY FTIR SPECTROSCOPY OF INTERLAYER NH+4 CATIONS | |
dc.type | Статья |
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