THERMAL EXPANSION OF MG(OH)2 BRUCITE UNDER HIGH PRESSURE AND PRESSURE DEPENDENCE OF ENTROPY

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dc.contributor.author Fukui H.
dc.contributor.author Ohtaka O.
dc.contributor.author Suzuki T.
dc.contributor.author Funakoshi K.
dc.date.accessioned 2022-02-13T04:46:09Z
dc.date.available 2022-02-13T04:46:09Z
dc.date.issued 2003
dc.identifier https://elibrary.ru/item.asp?id=5108138
dc.identifier.citation Physics and Chemistry of Minerals, 2003, 30, 9, 511-516
dc.identifier.issn 0342-1791
dc.identifier.uri https://repository.geologyscience.ru/handle/123456789/35277
dc.description.abstract An equation of state for Mg(OH)2 brucite under high-pressure and high-temperature conditions has been obtained by measuring temperature dependence of volume up to 600 K at ambient pressure and pressure dependence of volume up to 16 GPa at 300, 473, 673, and 873 K with in situ X-ray diffraction. Pressure dependence of entropy of brucite has been calculated with thermal expansion coefficient and volume which are derived from the present EoS. This dependence indicates that generation of secondary OH dipoles affects entropy. The OH dipoles probably appear around 2 GPa and the number seems not to change over 8 GPa at 300 K.
dc.subject BRUCITE
dc.subject EQUATION OF STATE
dc.subject THERMAL EXPANSION
dc.subject ENTROPY
dc.subject X-RAY DIFFRACTION
dc.title THERMAL EXPANSION OF MG(OH)2 BRUCITE UNDER HIGH PRESSURE AND PRESSURE DEPENDENCE OF ENTROPY
dc.type Статья


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