INSIGHTS INTO ASTROPHYLLITE-GROUP MINERALS. I. NOMENCLATURE, COMPOSITION AND DEVELOPMENT OF A STANDARDIZED GENERAL FORMULA
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dc.contributor.author | Piilonen P.C. | |
dc.contributor.author | Lalonde A.E. | |
dc.contributor.author | McDonald A.M. | |
dc.contributor.author | Gault R.A. | |
dc.contributor.author | Larsen A.O. | |
dc.date.accessioned | 2022-02-19T06:47:04Z | |
dc.date.available | 2022-02-19T06:47:04Z | |
dc.date.issued | 2003 | |
dc.identifier | https://elibrary.ru/item.asp?id=13917474 | |
dc.identifier.citation | The Canadian Mineralogist, 2003, 41, 1, 1-26 | |
dc.identifier.issn | 0008-4476 | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/35534 | |
dc.description.abstract | The composition of 135 samples of astrophyllite-group minerals from 15 localities has been established by EMPA, ICP-AES, FTIR, TGA, thermal decomposition, NRA and Mössbauer spectroscopy. A standardized general formula has been developed and is of the form A2BC7D2T8O26(OH 4X0-1, where [10]-[13]A = K, Rb, Cs, H3O+, H2O, Na or □; [10]B = Na or Ca; [6]C = Mn, Fe2+, Fe3+, Na, Mg, or Zn; [6]D = Ti, Nb, or Zr; [4]T = Si or Al, X = Φ = F, OH, O, or □. Data acquired by Mössbauer spectroscopy, thermodynamic approximations, and EMP analyses have been used to demonstrate that F orders at the Φ(16) site and does not occur at the two general OH sites within the O sheet. On this basis, formulas of the eight species of astrophyllite-group minerals have been redefined. Results from Mössbauer spectroscopy indicate Fe3+/Fetot values in the range from 0.01 to 0.21, corresponding to 0.05 to 0.56 apfu Fe3+, confirming that Fe2+ is the dominant valence state for iron in the structure. Minerals from silica-oversaturated and -undersaturated alkaline intrusions are distinct in chemical composition. In oversaturated rocks, the dominant member of the group is astrophyllite sensu stricto, which occurs as a late-stage postmagmatic phase, enriched in Rb, Fe2+, Ti, Si and F. In contrast, undersaturated intrusions, in particular Mont Saint-Hilaire, Quebec, show the greatest diversity in species and range in chemical composition. Kupletskite-subgroup samples are enriched in Na, Mn, Fe3+, Zn, Zr and Nb, whereas astrophyllite-subgroup samples are enriched in K, Ca, Fe2+, Ti, Zr and Al. Enrichment of kupletskite-subgroup samples in Fe3+, Mn and Nb suggests crystallization under more oxidizing conditions than those of the astrophyllite subgroup. Incorporation of Nb into the structure and the formation of Nb-bearing kupletskite and niobokupletskite are the result of the substitution M(I)2+ + M(2.3)2+ + (Zr, Ti) + F ⇔ M(1)Na + M(2.3)Fe3+ + Nb + O. | |
dc.subject | astrophyllite-group minerals | |
dc.subject | kupletskite subgroup | |
dc.subject | astrophyllite subgroup | |
dc.subject | structural formula | |
dc.subject | crystal chemistry | |
dc.title | INSIGHTS INTO ASTROPHYLLITE-GROUP MINERALS. I. NOMENCLATURE, COMPOSITION AND DEVELOPMENT OF A STANDARDIZED GENERAL FORMULA | |
dc.type | Статья |
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