COMPUTER SIMULATION OF OCTAHEDRAL CATION DISTRIBUTION AND INTERPRETATION OF THE MöSSBAUER FE2+ COMPONENTS IN DIOCTAHEDRAL TRANS-VACANT MICAS
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dc.contributor.author | Dainyak L.G. | |
dc.contributor.author | Drits V.A. | |
dc.contributor.author | Lindgreen H. | |
dc.date.accessioned | 2022-03-30T02:31:56Z | |
dc.date.available | 2022-03-30T02:31:56Z | |
dc.date.issued | 2004 | |
dc.identifier | https://www.elibrary.ru/item.asp?id=13471320 | |
dc.identifier.citation | European Journal of Mineralogy, 2004, 16, 3, 451-468 | |
dc.identifier.issn | 0935-1221 | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/36762 | |
dc.description.abstract | Cation distributions (CDs) in the representative collection of trans-vacant dioctahedral celadonites, glauconites and ferriillites were investigated using Mössbauer and IR spectroscopies and the original approach. The approach is based on individual quadrupole splittings ipred for Fe3+ in possible local cation arrangements around Fe3+, and on a computer simulation of two-dimentional CDs using the IR data in the OH stretching vibration region. The resulting CDs were next used to make correlations between j of Fe2+ derived from computer fits to the corresponding spectra and cation composition of local cation arrangements around Fe2+ with their occurrence probabilities. Basing on this correlations, a total of eight individual itent for Fe2+ referred as "tentative" have been derived. The order of local cation arrangements in terms of increasing quadrupole splitting was found to be the same both for Fe3+ and Fe2+ and implies a direct dependence of the Fe2+ quadrupole splitting on the structural distortion at Fe2+ site. The set of itent for Fe2+ combined with ipred for Fe3+ and with the new CD simulation program provide an additional means for controlling the CD reconstruction. | |
dc.subject | celadonite | |
dc.subject | glauconite | |
dc.subject | ferriillite | |
dc.title | COMPUTER SIMULATION OF OCTAHEDRAL CATION DISTRIBUTION AND INTERPRETATION OF THE MöSSBAUER FE2+ COMPONENTS IN DIOCTAHEDRAL TRANS-VACANT MICAS | |
dc.type | Статья |
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