HYDROGEN SOLUBILITY AND SPECIATION IN NATURAL, GEM-QUALITY CHROMIAN DIOPSIDE
- DSpace Home
- →
- Геология России
- →
- ELibrary
- →
- View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.
dc.contributor.author | Bromiley G.D. | |
dc.contributor.author | McCammon C. | |
dc.contributor.author | Bromiley F.A. | |
dc.contributor.author | Jacobsen S.D. | |
dc.contributor.author | Keppler H. | |
dc.date.accessioned | 2022-04-04T07:16:54Z | |
dc.date.available | 2022-04-04T07:16:54Z | |
dc.date.issued | 2004 | |
dc.identifier | https://www.elibrary.ru/item.asp?id=13804760 | |
dc.identifier.citation | American Mineralogist, 2004, 89, 7, 941-949 | |
dc.identifier.issn | 0003-004X | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/36856 | |
dc.description.abstract | A new technique for performing long duration (up to 300 hours) high-pressure annealing experiments under water-saturated conditions has been developed. This technique has been used to investigate water-solubility and speciation in natural, gem-quality chromian diopside. Capsule design for the technique is a variant of the double-capsule technique, and relies on the use of a semi-permeable Pt membrane, which permits free hydrogen diffusion into samples, but protects samples from reacting with buffer mixtures. The investigation of a natural single crystal of chromian diopside revealed a very unusual annealing behavior: water contents increase sharply after a short annealing period and then decrease slowly to some metastable equilibrium value. The main process that takes place during the annealing experiments is hydrogen diffusion coupled with Fe3+ reduction. This essentially reverses the main mechanism for hydrogen loss from mantle samples during exhumation, and the technique therefore provides sample-specific information on original water contents. Absorption bands at 3646 and 3434 cm-1 in IR spectra from annealed samples suggest two main mechanisms for hydrogen incorporation in the diopside sample: (1) incorporation of hydrogen onto the 02 site, with vibration of the OH dipole in the direction of a nearby 03 site (along the edge of an M2 site), and (2) incorporation of hydrogen onto the 02 site with vibration of the OH dipole toward a nearby 01 site (along a shared M1-M2 edge) or 02 site (along the edge of an MI site). The ratio of peak heights between the absorption bands at 3646 and 3434 cm-1 is independent of water fugacity but dependent on oxygen fugacity, and appears to provide a measure of the redox state "frozen" into the sample. This ratio could be used to determine whether pyroxenes from upper-mantle xenoliths had experienced concurrent hydrogen-loss and oxidation during exhumation. | |
dc.subject | diopside | |
dc.title | HYDROGEN SOLUBILITY AND SPECIATION IN NATURAL, GEM-QUALITY CHROMIAN DIOPSIDE | |
dc.type | Статья |
Files in this item
This item appears in the following Collection(s)
-
ELibrary
Метаданные публикаций с сайта https://www.elibrary.ru