PHASE TRANSITION AND COMPRESSION BEHAVIOR OF GIBBSITE UNDER HIGH-PRESSURE

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dc.contributor.author Liu H.
dc.contributor.author Hu J.
dc.contributor.author Xu J.
dc.contributor.author Liu Z.
dc.contributor.author Shu J.
dc.contributor.author Mao H.K.
dc.contributor.author Chen J.
dc.date.accessioned 2022-10-31T00:38:50Z
dc.date.available 2022-10-31T00:38:50Z
dc.date.issued 2004
dc.identifier https://www.elibrary.ru/item.asp?id=6470603
dc.identifier.citation Physics and Chemistry of Minerals, 2004, 31, 4, 240-246
dc.identifier.issn 0342-1791
dc.identifier.uri https://repository.geologyscience.ru/handle/123456789/39294
dc.description.abstract In situ high-pressure synchrotron X-ray diffraction and infrared absorption experiments for gibbsite were performed at room temperature up to 53 and 25 GPa, respectively. A phase transition was confirmed at about 2.5 GPa. The high-pressure phase is indexed as an orthorhombic structure, rather than a triclinic structure as reported in previous studies. The compressibility of gibbsite and its high-pressure polymorph were studied, and their bulk moduli K0 were determined to be 49 and 75 GPa, respectively with K0' as 4. The in situ high-pressure infrared absorption spectra revealed the gradual disordering of hydrogen substructure above 15 GPa in quasihydrostatic compression.
dc.subject AL(OH)3
dc.subject HIGH-PRESSURE
dc.subject PHASE TRANSITION
dc.subject X-RAY DIFFRACTION
dc.subject INFRARED ABSORPTION
dc.title PHASE TRANSITION AND COMPRESSION BEHAVIOR OF GIBBSITE UNDER HIGH-PRESSURE
dc.type Статья


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