OXIDATION OF 1-NAPHTHOL COUPLED TO REDUCTION OF STRUCTURAL FE3+ IN SMECTITE
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dc.contributor.author | Arroyo L.J. | |
dc.contributor.author | Li H. | |
dc.contributor.author | Teppen B.J. | |
dc.contributor.author | Boyd S.A. | |
dc.contributor.author | Johnston C.T. | |
dc.date.accessioned | 2023-12-03T03:59:57Z | |
dc.date.available | 2023-12-03T03:59:57Z | |
dc.date.issued | 2005 | |
dc.identifier | https://www.elibrary.ru/item.asp?id=14674637 | |
dc.identifier.citation | Clays and Clay Minerals, 2005, 53, 6, 587-596 | |
dc.identifier.issn | 0009-8604 | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/42108 | |
dc.description.abstract | Sorption and transformation of 1-naphthol by a K-smectite (K-SWy-2) were studied using batch sorption isotherms, Fourier-transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). The sorbents included three preparations of the reference smectite clay (SWy-2): (1) whole clay containing naturally occurring carbonate impurities, (2) SWy-2 with the removal of carbonate impurities, and (3) the carbonate-free SWy-2 fraction amended with calcite. For the whole clay and carbonate-free clay amended with calcite, >80% of added 1-naphthol disappeared from aqueous solution within 24 h, corresponding to a sorbed concentration of ≥2 mg/g of clay. In contrast, only 35% of the added 1-naphthol disappeared from solution in the carbonate-free clay after 24 h of exposure. For the clays from the three preparations in this study, 3+ reduction. The spectra also showed evidence of the transformation of 1-naphthol. It suggests that reduction of structural Fe3+ may be coupled to oxidation/polymerization of 1-naphthol. Further transformation of oxidized 1-naphthol, such as by oxidative coupling reactions, is implicated by formation of a dark gray color on the clay and the inability to extract sorbed 1-naphthol. | |
dc.subject | smectite | |
dc.title | OXIDATION OF 1-NAPHTHOL COUPLED TO REDUCTION OF STRUCTURAL FE3+ IN SMECTITE | |
dc.type | Статья | |
dc.identifier.doi | 10.1346/CCMN.2005.0530605 |
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