SOLUTION MECHANISMS OF H2O IN DEPOLYMERIZED PERALKALINE MELTS
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dc.contributor.author | Mysen B.O. | |
dc.contributor.author | Cody G.D. | |
dc.date.accessioned | 2023-12-30T07:21:42Z | |
dc.date.available | 2023-12-30T07:21:42Z | |
dc.date.issued | 2005 | |
dc.identifier | https://www.elibrary.ru/item.asp?id=31354942 | |
dc.identifier.citation | Geochimica et Cosmochimica Acta, 2005, 69, 23, 5557-5566 | |
dc.identifier.issn | 0016-7037 | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/42404 | |
dc.description.abstract | Solubility mechanisms of water in depolymerized silicate melts quenched from high temperature (1000°-1300°C) at high pressure (0.8-2.0 GPa) have been examined in peralkaline melts in the system Na2 O-SiO2-H2O with Raman and NMR spectroscopy. The Na/Si ratio of the melts ranged from 0.25 to 1. Water contents were varied from ~3 mol% and ~40 mol% (based on O = 1). Solution of water results in melt depolymerization where the rate of depolymerization with water content, ∂(NBO/Si)/∂ XH2O, decreases with increasing total water content. At low water contents, the influence of H2O on the melt structure resembles that of adding alkali oxide. In water-rich melts, alkali oxides are more efficient melt depolymerizers than water. In highly polymerized melts, Si-OH bonds are formed by water reacting with bridging oxygen in Q4-species to form Q3 and Q2 species. In less polymerized melts, Si-OH bonds are formed when bridging oxygen in Q3-species react with water to form Q2-species. In addition, the presence of Na-OH complexes is inferred. Their importance appears to increase with Na/Si. This apparent increase in importance of Na-OH complexes with increasing Na/Si (which causes increasing degree of depolymerization of the anhydrous silicate melt) suggests that water is a less efficient depolymerizer of silicate melts, the more depolymerized the melt. This conclusion is consistent with recently published 1H and 29Si MAS NMR and 1H-29Si cross polarization NMR data. Copyright © 2005 Elsevier Ltd. | |
dc.subject | Solubility mechanisms | |
dc.subject | water | |
dc.subject | silicate melt | |
dc.title | SOLUTION MECHANISMS OF H2O IN DEPOLYMERIZED PERALKALINE MELTS | |
dc.type | Статья | |
dc.identifier.doi | 10.1016/j.gca.2005.07.020 |
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