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ELibrary: Recent submissions
Now showing items 801-820 of 22596
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(2006)In a previous contribution, we outlined a method for predicting (hydr)oxy-acid and oxide surface acidity constants based on three main factors: bond valence, Me-O bond ionicity, and molecular shape. Here, electrostatics ...
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(2006)Detailed understanding of the respective roles of solution and surface parameters on the reactions at uranyl solution/Al-(hydr)oxide interfaces is crucial to model accurately the behaviour of U in nature. We report studies ...
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(2006)The kinetics of smectite illitization in shale samples from eight wells have been modeled using the equation -dS/dt = kK0.25S5 [Cuadros, J., Linares J., 1996. Experimental kinetic study of the smectite-to-illite transformation. ...
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(2006)Plant litter decomposition plays a fundamental role in carbon and nitrogen cycles, provides key nutrients to the soil environment and represents a potentially large positive feedback to atmospheric CO2. However, the full ...
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(2006)We propose a theory for crystal-melt trace element partitioning that considers the energetic consequences of crystal-lattice strain, of multi-component major-element silicate liquid mixing, and of trace-element activity ...
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(2006)We measured the 153Eu/151Eu ratio by MC-ICP-MS for a terrestrial basalt, two terrestrial soils, and four meteorites (whole rocks and/or chondrules of Bjurb?le, Forest City, Murchison, and Allende) and found no isotopic ...
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(2006)Estimation of the framework connectivity and the atomic structure of depolymerized silicate melts and glasses (NBO/T > 0) remains a difficult question in high-temperature geochemistry relevant to magmatic processes and ...
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(2006)The behaviour of trace amounts of arsenate coprecipitated with ferrihydrite, lepidocrocite and goethite was studied during reductive dissolution and phase transformation of the iron oxides using [55Fe]- and [73As]-labelled ...
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(2006)The influence of solution complexation on the sorption of yttrium and the rare earth elements (YREEs) by amorphous ferric hydroxide was investigated at 25 °C over a range of pH (4.0-7.1) and carbonate concentrations (0 M ...
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(2006)Organic ligands affect the sorption and mobility of radionuclides in soils. Batch desorption experiments on goethite particles reveal the extent of uranyl desorption and hence bioavailability with different organic acids. ...
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(2006)A theoretical model was developed to explain the characteristics of carbon isotopic fractionation (?P) by the marine diatom Phaeodactylum tricornutum under nutrient- and light-limited growth conditions. The model takes ...
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(2006)Atmospheric argon measured on a dynamically operated mass spectrometer with an ion source magnet, indicated systematically larger 40Ar/36Ar ratios compared to the generally accepted value of Nier [Nier A.O., 1950. A ...
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(2006)Phosphonoformic acid, oxalic acid, glyoxylic acid, and 10 additional organic compounds that are structurally related to them have been reacted with synthetic MnO2 (birnessite), consisting of 22% MnIII and 78% MnIV, and ...
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(2006)Electron transfer between redox active proteins and mineral oxides is important in a variety of natural as well as technological processes, including electron transfer from dissimilatory metal-reducing bacteria to minerals. ...
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(2006)The 44Ca/40Ca ratios of cultured (Acropora sp.) and open ocean (Pavona clavus, Porites sp.) tropical reef corals are positively correlated with growth temperature. The slope of the temperature-fractionation relation is ...
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(2006)The steady state dissolution rate of San Carlos olivine [Mg1.82Fe0.18 SiO4] in dilute aqueous solutions was measured at 90, 120, and 150 °C and pH ranging from 2 to 12.5. Dissolution experiments were performed in a stirred ...
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(2006)The basal plane reactivities of the sheet silicates apophyllite and phlogopite have been studied by hydrothermal atomic force microscopy (HAFM) in situ in aqueous solutions at temperatures from 20 to 140 °C. At pH 4-5.6 ...
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(2006)Several recent studies have applied surface complexation theory to model metal adsorption behaviour onto mesophilic bacteria. However, no investigations have used this approach to characterise metal adsorption by thermophilic ...
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(2006)U-series radioactive disequilibria in basaltic lavas have been used to infer many important aspects of melt generation and extraction processes in Earth’s mantle and crust, including the porosity of the melting zone, the ...
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(2006)Biotite is widely used for Rb-Sr and K-Ar isotopic dating and influences Sr isotope geochemistry of hydrological regimes. The isotopic system of biotite behaves diversely in response to surface weathering; i.e. the complete ...
Now showing items 801-820 of 22596