APPARENT ARGON DIFFUSIVE LOSS 40AR39AR AGE SPECTRA IN AMPHIBOLES

Abstract

Detailed investigations have been made of two amphibole samples where 40Ar39Ar age spectra have been interpreted to show argon diffusive loss. Both samples display complex compositional zoning that reflects partial major and minor element chemical re-equilibration during later thermal events that is associated with the loss of radiogenic 40Ar. The apparent diffusive loss age spectra in these samples are an artefact of this chemical re-equilibration process. One sample additionally shows the effect of potassium gain and contamination with a potassium-rich phase (biotite). The resulting ages in this sample are geologically meaningless and the apparent fit to a theoretical diffusive loss curve is coincidental. This study shows that volume diffusive loss of argon appears to operate at slower rates than argon loss by chemical re-equilibration in amphiboles.