DIRECT OBSERVATIONS OF NONINTEGRAL HYDROUS FERRIC OXIDE SOLUBILITY PRODUCTS: K*S0=[FE3+][H+]-2.86
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dc.contributor.author | Byrne R.H. | |
dc.contributor.author | Luo Y.R. | |
dc.date.accessioned | 2021-01-23T00:52:15Z | |
dc.date.available | 2021-01-23T00:52:15Z | |
dc.date.issued | 2000 | |
dc.identifier | https://elibrary.ru/item.asp?id=252827 | |
dc.identifier.citation | Geochimica et Cosmochimica Acta, 2000, 64, 11, 1873-1877 | |
dc.identifier.issn | 0016-7037 | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/23576 | |
dc.description.abstract | Previous studies have indicated that hydrous ferric oxide precipitates, formed and aged at low temperatures, exhibit solubility products of the form K*S0 = [Fe3+][H+]-m, where m < 3 ([ ] # free ion concentration). Although previous observations have either been obtained over a very narrow pH range or have involved phase separations and solution chemical modeling, the present work involves direct potentiometric observations of log [Fe3+] and log [H+] over a wide range of Fe3+ concentrations and pH. Our observations obtained at 25°C in 0.7 molar NaClO4 provide substantial evidence for log [Fe3+] vs. pH relationships with slopes (m) smaller than three but larger than those obtained in previous works (m = 2.70 and m = 2.35). Over a four unit range in pH and a nearly 12 order of magnitude range in [Fe3+] the observed relationship between pH and log [Fe3+] in this work is log [Fe3+] = 4.28 +/- 0.05 - (2.86 +/- 0.009) pH. This solubility behavior has substantial implications for the behavior of FeIII in natural waters. | |
dc.title | DIRECT OBSERVATIONS OF NONINTEGRAL HYDROUS FERRIC OXIDE SOLUBILITY PRODUCTS: K*S0=[FE3+][H+]-2.86 | |
dc.type | Статья |
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