Abstract:
Ten reversed brackets of aqueous silica concentration in equilibrium with enstatite (Mg2Si2O6) and forsterite (Mg2SiO4) were determined at 700 to 900°C and 4.35 to 14 kbar. Silica solubilities were measured by a weight loss-weight gain method and by approaching equilibrium from higher and lower silica concentrations. Both single-crystal and fine-grained synthetic enstatite and forsterite starting material were used, as well as low-Fe natural minerals. Results for all three kinds of starting material were concordant. Silica concentrations buffered by enstatite + forsterite at 10 kbar increase from 0.16 moles/kg H2O (m) at 700°C to 0.50 m at 900°C, but show only small variation with pressure in the range 7 to 14 kbar. The ratio XSQ/XSFE, where XSQ is the mole fraction of aqueous SiO2 (S) in equilibrium with quartz (Q) from , and XSFE is the corresponding mole fraction in equilibrium with forsterite (F) and enstatite (E) at the same P and T, from 1 to 15 kbar and 700 to 900°C is described byXSQXSFE=2.61-0.000930T+0.0236P+290PTwhere P is in kbar and T in Kelvins. All of our measured silica solubilities are significantly lower than predicted with the conventional assumption of unit activity of silica for concentrations from zero to quartz saturation. Aqueous silica therefore exhibits negative, composition-dependent departures from ideality, in agreement with the deduction of based on measurements at higher temperatures. suggested that the formation of solute silica dimers accounts for the lowered activity. The equilibrium constant, K, for the proposed dimer formation reaction, 2H4SiO4 = H6Si2O7 + H2O, is K = XdimersaH2O/Xmonomers2, where the activities (a) of solute species are equated with their mole fractions, and aH20 ~ 1 at the low SiO2 concentrations considered. Our solubility data at 700°C and 10 kbar give logK = 2.2, which predicts that solute silica in equilibrium with quartz at these conditions is about 40% polymerized, assuming dimers are the only polymer species. This estimate is in good agreement with Raman spectroscopic results of . However, if higher polymers, including rings and chains, are also present, the estimates of K based on either the solubility measurements or the spectroscopic observations would be substantially smaller. Our solubility measurements show that the activity of aqueous silica is substantially less than the molar concentration at deep crust/upper mantle PT conditions.
