Abstract:
The petrography and mineral chemistry of 110 Ca-, Al-rich inclusions (CAIs) and 9 Ca- and/or Al-rich amoeboid olivine aggregates (AOAs) from the Ningqiang carbonaceous chondrite are reported. These CAIs are referred to as hibonite-bearing and hibonite-free melilite–spinel–rich (Type A), and spinel–pyroxene inclusions. Melilite is more gehlenitic in the hibonite-bearing Type As than in the other two types, and all of them vary within a range of Åk0–30. Modal compositions of the three types of CAIs overlap with each other, and make up a continuum with wide ranges of melilite: spinel: diopside. The diopside occurs as rims on the CAIs or their individual concentric objects. The 9 AOAs contain spinel ± diopside ± anorthite in the centers of the aggregates; the spinel grains rimmed by diopside in the centers are similar to the spinel–pyroxene inclusions. Bulk compositions of these CAIs vary along the condensation trajectory, with the hibonite-bearing Type As plotting at the beginning followed by hibonite-free Type As then by spinel–pyroxene inclusions as temperature decreases. Bulk compositions of the AOAs are close to the lowest temperature condensation trajectory. Except for a few with compact textures, most of the Type As and spinel–pyroxene inclusions are fluffy aggregates, probably pristine vapor-solid condensates of the nebula.The bulk compositions of the Type As appear to overlap with the range of most melilite–Ti–Al–clinopyroxene–rich (Type B) inclusions. Hence, crystallization of liquids produced by melting the Type As can form Type B inclusions, without significant evaporative loss of MgO or SiO2. A few Type Bs have bulk compositions deviating from the range of their proposed precursors, and may have suffered significant evaporation, as suggested in previous studies.
