ANISOTROPIC COMPRESSION OF EDINGTONITE AND THOMSONITE TO 6 GPA AT ROOM TEMPERATURE
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dc.contributor.author | Lee Y. | |
dc.contributor.author | Vogt T. | |
dc.contributor.author | Hriljac J.A. | |
dc.contributor.author | Studer A. | |
dc.date.accessioned | 2022-11-08T06:07:42Z | |
dc.date.available | 2022-11-08T06:07:42Z | |
dc.date.issued | 2004 | |
dc.identifier | https://www.elibrary.ru/item.asp?id=14374782 | |
dc.identifier.citation | Physics and Chemistry of Minerals, 2004, 31, 1, 22-27 | |
dc.identifier.issn | 0342-1791 | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/39603 | |
dc.description.abstract | Polycrystalline samples of natural edingtonite (New Brunswick, Canada) and thomsonite (Oregon, USA) were studied up to 6 GPa using monochromatic synchrotron X-ray powder diffraction and a diamond-anvil cell with a methanol:ethanol:water mixture as a penetrating pressure-transmitting fluid. Unlike natrolite, previously studied under the same conditions, edingtonite and thomsonite do not show any apparent pressure-induced hydration (PIH) or phase transitions. All these fibrous zeolites are characterized by their anisotropic compressibilities, with the linear compressibilities of the fibrous chains (c-axis) being as small as one third of those perpendicular to the chains (a-, b-axes); for edingtonite, β0a =0.0050(3) GPa−1, β0b =0.0054(2) GPa−1, β0c =0.0034(1) GPa−1; for thomsonite, β0a = 0.0080(2) GPa−1, β0b =0.0084(2) GPa−1, β0c =0.0032(1) GPa−1. The pressure–volume data were fitted to a second-order Birch–Murnaghan equation of state using a fixed pressure derivative of 4. As a result of the 0000-type connectivity of the chains, the bulk modulus of edingtonite is found to be about 40% larger than that of thomsonite; KEDI0=73(3) GPa, KTHO0=52(1) GPa. Distance least-squares refinements were used to model the expected framework, following the observed linear compression behaviors. The chain-bridging T–O–T angle is proposed to be correlated with the different compressibilities across the chains in each framework type. | |
dc.subject | Edingtonite | |
dc.subject | Thomsonite | |
dc.subject | High pressure | |
dc.subject | Anisotropic compression | |
dc.subject | Bulk modulus | |
dc.subject | Distance least-squares | |
dc.title | ANISOTROPIC COMPRESSION OF EDINGTONITE AND THOMSONITE TO 6 GPA AT ROOM TEMPERATURE | |
dc.type | Статья |
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