CRYSTAL STRUCTURE OF A SYNTHETIC ALUMINOAN TANTALIAN TITANITE: A RECONNAISSANCE STUDY
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dc.contributor.author | Liferovich R.P. | |
dc.contributor.author | Mitchell R.H. | |
dc.date.accessioned | 2024-07-14T10:19:03Z | |
dc.date.available | 2024-07-14T10:19:03Z | |
dc.date.issued | 2006 | |
dc.identifier | https://elibrary.ru/item.asp?id=13504029 | |
dc.identifier.citation | Mineralogical Magazine, 2006, Vol. 70(1), pp. 115-121 | |
dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/44412 | |
dc.description.abstract | A synthetic analogue, Ca(Ti 0.6Al 0.2Ta 0.16 Nb 0.04 )OSiO 4, of an aluminoan tantalian titanite previously described from Craveggia pegmatite (Piemonte, Italy) has been prepared by a ceramic synthesis technique and its crystal structure determined by Rietveld analysis of the powder X-ray diffraction pattern. The synthetic Al-Ta-Nb-rich titanite adopts space group A2/a implying that substitutions at the single octahedral site destroy the coherence of the off-centering of octahedral chains in the titanite structure resulting in a P2 1/a ? A2/a phase transition. Unit-cell dimensions obtained for the Al-Ta-Nb-rich titanite are: a = 7.0649(1) AÊ ; b = 8.7187(1) AÊ ; c = 6.5701(1) AÊ ; û = 113.755(1)ë, V = 370.41(1) AÊ 3. The extensive replacement of Ti by Al, Ta and Nb results in a considerable decrease in the distortion of all coordination polyhedra in the structure of this titanite. These structural data suggest that a solid solution CaTi 1ÿx(Alx/2 [Ta,Nb]x/2 )OSiO 4 (0 4 x 4 0.4) adopting the titanite structure might exist. | |
dc.subject | titanite | |
dc.subject | Rietveld analysis | |
dc.subject | crystal structure | |
dc.subject | distortion | |
dc.subject | tantalum | |
dc.subject | niobium | |
dc.subject | aluminium | |
dc.title | CRYSTAL STRUCTURE OF A SYNTHETIC ALUMINOAN TANTALIAN TITANITE: A RECONNAISSANCE STUDY | |
dc.type | Статья | |
dc.identifier.doi | 10.1180/0026461067010317 |
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