FE AND NI IMPURITIES IN SYNTHETIC DIAMOND
| dc.contributor.author | Meng Y. | |
| dc.contributor.author | Newville M. | |
| dc.contributor.author | Sutton S. | |
| dc.contributor.author | Rakovan J. | |
| dc.contributor.author | Mao H.-K. | |
| dc.date.accessioned | 2021-11-28T04:25:34Z | |
| dc.date.available | 2021-11-28T04:25:34Z | |
| dc.date.issued | 2003 | |
| dc.description.abstract | Using synchrotron X-ray fluorescence (XRF) microanalysis, including XRF tomography, and X-ray absorption near-edge structure (XANES) analyses, the distribution, and nature of incorporation of Fe and Ni impurities in as-grown diamond crystals, synthesized under high-pressure and high-temperature (HPHT) conditions, have been characterized. We find significantly different behavior for Fe and Ni as impurities in diamond. Nickel is dispersed and sector-zoned, with concentrations in {111} growth sectors at least 3 times those in {100} sectors, whereas Fe exists in the form of micro-aggregates or clusters with no observable sector correlation. Fe K-edge XANES shows that Fe is oxidized in diamond and has a valence of 2+. Comparison of XANES spectra from numerous standard compounds indicates that Fe is very likely bonded with oxygen as FeO. | |
| dc.identifier | https://www.elibrary.ru/item.asp?id=14175974 | |
| dc.identifier.citation | American Mineralogist, 2003, 88, 10, 1555-1559 | |
| dc.identifier.issn | 0003-004X | |
| dc.identifier.uri | https://repository.geologyscience.ru/handle/123456789/32538 | |
| dc.subject | Diamond | |
| dc.title | FE AND NI IMPURITIES IN SYNTHETIC DIAMOND | |
| dc.type | Статья |