HIGH-TEMPERATURE CREEP IN A NI2GEO4 CONTRIBUTION TO CREEP SYSTEMATICS IN SPINEL
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HIGH-TEMPERATURE CREEP IN A NI2GEO4 CONTRIBUTION TO CREEP SYSTEMATICS IN SPINEL
Lawlis J.D.; Zhao Y.H.; Karato S.
xmlui.dri2xhtml.METS-1.0.item-citation:
Physics and Chemistry of Minerals, 2001, 28, 8, 557-571
Date:
2001
Abstract:
High-temperature creep behavior in Ni2GeO4 spinel was investigated using synthetic polycrystalline aggregates with average grain sizes ranging from submicron to 7.4 microns. Cylindrical samples were deformed at constant load in a gas-medium apparatus at temperatures ranging from 1223 to 1523 K and stresses ranging from 40 to 320 MPa. Two deformation mechanisms were identified, characterized by the following flow laws: where σ is in MPa, d is in μm and T is in Kelvin. These flow laws suggest that deformation was accommodated by dislocation creep and grain-boundary diffusion (Coble) creep, respectively. A comparison with other spinels shows that an isomechanical group can be defined for spinels although some differences between normal and inverse spinels can be identified. When creep data for olivine and spinel are normalized and extrapolated to Earth-like conditions, spinel (ringwoodite) has a strength similar to olivine in the dislocation creep regime and is considerably stronger than olivine in the diffusion creep regime at coarse grain size. However, when grain-size reduction occurs, spinel can become weaker than olivine due to its high grain-size sensitivity (Coble creep behavior). Analysis of normalized diffusion creep data for olivine and spinel indicate that spinel is weaker than olivine at grain sizes less than 2 μm.
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