Abstract:
Some hotspot volcanism is likely the surface manifestation of hot upwelling mantle plumes that rise from the core–mantle boundary (CMB) or from compositional boundaries within the mantle. Plumes that rise from the CMB may generate magmas that carry compositional information about the diversity of materials present in the lowermost mantle. Some plume-derived materials have coupled enrichments in 186Os/188Os and 187Os/188Os relative to upper mantle materials. The coupled enrichments are consistent with Os isotopic compositions predicted for the liquid outer core that might result from elevated Pt/Os and Re/Os generated via progressive crystallization of a solid inner core over Earth history. If these enrichments are a reflection of core–mantle interaction, then the mechanisms of material transport between the core and the mantle, rates of whole mantle convection at present and over time, and cooling histories for the core and the mantle can potentially be constrained. However, fractionation may also occur between Pt/Re/Os via mantle and crustal processes and in particular, Pt and Pt/Re may be elevated in some portions of ancient recycled slabs thought to be present in certain plume sources. This possibility brings into question whether the coupled Os isotope enrichments are a product of core–mantle exchange. Hence, a lively debate over the causes of Os isotopic heterogeneities in plume-derived materials has ensued. Resolution of this debate has been hampered by limited constraints on the behavior of these elements in the Earth’s core, mantle and crust. Avariety of analytical and experimental tasks will have to be pursued to test different aspects of both the core–mantle interaction and crustal recycling models, and to further constrain the behaviors of these elements. These future endeavors may help to unravel the compositional complexities of plume-derived materials and their mantle sources, and ultimately provide important insights to processes operating at the CMB.
